Full List of Publications with TOC

Main content

2017

137
136

(135) Osuna Gálvez, A.; Schaack, C. P.; Noda, H.; Bode, J. W. "Chemoselective acylation of primary amines and amides with potassium acyltrifluoroborates under acidic conditions" J. Am. Chem. Soc. 2017, 139, 1826–1829
highlighted in Org. Process Res. Dev. 201721, 279–291

135

(134) Oriana, S.; Ye, C.; Bode, J. W.; Yamakoshi, Y. "Synthesis of tri-functionalized MMP2 FRET probes using a chemo-selective and late-stage modification of unprotected peptides" Org. Biomol. Chem. 201715, 1792-1800

133
132
130

2016

131

(129) Book chapter: Chiang, P.-C.; Bode, J. W. "N-Heterocyclic Carbenes as Organic Catalysts" N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools (Edition 2) [Ed: Silvia Diez-Gonzalez]

(128) Perspective: Saito, F.; Bode, J. W. "Macrocyclic Peptides: Tying Up Loose EndsNature Chem. 2016, 8, 1085-1086

128

(127) Perspective: Hofmann, R.; Bode, J. W. "A Radical Approach to Posttranslational Mutagenesis" Science 2016354, 553–554. 

127

(126) Liu, S. M.; Mazunin, D.; Pattabiraman, V. R.; Bode, J. W.; "Synthesis of Bifunctional Potassium Acyltrifluoroborates" Org. Lett. 2016, 18, 5336–5339

125

(125) Thuaud, F.; Rohrbacher, F.; Zwicky, A.; Bode, J. W.; "Photoprotected Peptide α-Ketoacids and Hydroxylamines for Iterative and One-Pot KAHA Ligations: Synthesis of NEDD8" Helv. Chim. Acta 2016, 99, 868–894

125

(124) Trindade, A. F.; Bode, J. W.; "Irreversible Conjugation of Aldehydes in Water To Form Stable 1,2,4-Oxadiazinan-5-ones" Org. Lett. 201618, 4210–4213

124

(123) Wucherpfennig, T. G.; Müller, S; Wolfrum, C.; Bode, J. W.; "Chemical Synthesis of the 12 kDa Human Myokine Irisin by α-Ketoacid-Hydroxylamine (KAHA) Ligation" Helv. Chim. Acta 201699, 897–907

123

(122) Thuaud, F.; Rohrbacher, F.; Zwicky, A.; Bode, J. W.; "Incorporation of Acid-Labile Masking Groups for the Traceless Synthesis of C-Terminal Peptide α-Ketoacids" Org. Lett. 201618, 3670–3673

122

(121) Harmand, T. J.; Murar, C. E.; Bode, J. W.; "Protein chemical synthesis by α-ketoacid-hydroxylamine ligation" Nature Protocols 2016, 11, 1130-1147

121
120

(119) Hsieh, S.-Y.; Bode, J. W.; "Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones" Org. Lett. 201618, 2098–2101

119

(118) Jackl, M. K.; Kreituss, I.; Bode J. W.; "Synthesis of Tetrahydronaphthyridines from Aldehydes and HARP Reagents via Radical Pictet–Spengler Reactions" Org. Lett. 2016, 18, 1713–1715
reviewed in Synfacts 201612, 0569

(117) Kreituss, I.; Chen, K.-Y.; Eitel, S. H.; Adam, J.-M.; Wuitschik, G.;Fettes, A.; Bode, J. W. "A Robust, Recyclable Resin for Decagram Scale Resolution of (±)-Mefloquine and Other Chiral N-Heterocycles" Angew. Chem. Int. Ed. 2016, 55, 1553–1556.
reviewed in Synfacts 201612, 0422. 

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2015

(115) He, C.; Kulkarni, S. S.; Thuaud, F.; Bode, J. W. "Chemical Synthesis of the 20 kDa Heme Protein Nitrophorin 4 by α-Ketoacid-Hydroxylamine (KAHA) Ligation" Angew. Chem. Int. Ed. 2015, 54, 12996–13001.

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(114) Wanner, B.; Kreituss, I.; Gutierrez, O.; Kozlowski, M. C.; Bode, J. W. "Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights" J. Am. Chem. Soc. 2015137, 11491–11497.

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(113) Review article: Luescher, M. U.; Geoghegan, K.; Nichols, P. L.; Bode, J. W. "SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles"Aldrichim. Acta 201548, 43–48.

(112) Luescher, M. U.; Bode, J. W. "Catalytic Synthesis of N-Unprotected Piperazines, Morpholines, and Thiomorpholines from Aldehydes and SnAP Reagents" Angew. Chem. Int. Ed. 201554, 10884–10888.
- SnAP reagents are commercially available on SIGMA-ALDRICH!

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(111)  Pusterla, I.; Bode, J. W. "An oxazetidine amino acid for chemical protein synthesis by rapid, serine-forming ligations" Nature Chem. 20157, 668–672.
- reviewed in Synform 2016, 02, A29-A31

111

(110) Rohrbacher, F.; Deniau, G.; Luther, A.; Bode, J. W. "Spontaneous Head-to-Tail Cyclization of Unprotected Linear Peptides with the KAHA Ligation" Chem. Sci. 20156, 4889–4896.

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(109) Mazunin, D.; Broguiere, N.; Zenobi-Wong, M.; Bode, J. W. "Synthesis of Biocompatible PEG Hydrogels by pH-Sensitive Potassium Acyltrifluoroborate (KAT) Amide Ligations" ACS Biomater. Sci. Eng. 20151, 456–462.

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(108) Geoghegan, K.; Bode, J. W. "Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles" Org. Lett. 201517, 1934–1937.
- SnAP reagents are commercially available on SIGMA-ALDRICH!

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(107) Book chapter: Rohrbacher, F.; Wucherpfennig, T. G.; Bode, J. W. "Chemical Protein Synthesis with the KAHA Ligation" Top. Curr. Chem. 2015363, 1–32.

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(105) Harmand, T. J.; Kulkarni, S. S.; Bode, J. W. "Optimized Synthesis of a Cyanosulfurylide Linker for Fmoc-SPPS of C-Terminal Peptide α-Ketoacids" Tetrahedron Lett. 201556, 3477–3480.

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(104) Saito, F.; Noda, H.; Bode, J. W. "Critical evaluation and rate constants of chemoselective ligation reactions for stoichiometric conjugations in water" ACS Chem. Biol. 201510, 1026–1033.
- highlighted in Nat. Chem. Biol. 201511, 241.

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(103) Schäfer, G.; Leu, L.; Bode, J. W. "Synthesis of Unsymmetrical, gem-Disubstituted Bisamides" Heterocycles 201590, 1375–1386. (Special issue)
- Dedicated to Professor Isao Kuwajima on the occasion of his 77th birthday.

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2014

(102) Murar, C. E.; Thuaud, F.; Bode, J. W. "KAHA Ligations that form Aspartyl Aldehyde Residues as Synthetic Handles for Protein Modification and Purification" J. Am. Chem. Soc. 2014136, 18140–18148.

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(101) Siau, W.-Y.; Bode, J. W. "One Step Synthesis of Saturated Spirocyclic N-Heterocycles with SnAP Reagents and Ketones" J. Am. Chem. Soc. 2014136, 17726–17729.
- SnAP reagents are commercially available on SIGMA-ALDRICH!

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(100) Review article: Harmand, T. J. R.; Murar, C. E.; Bode, J. W. "New chemistries for chemoselective peptide ligations and the total synthesis of proteins" Curr. Opin. Chem. Biol. 201422, 115–121.

(99) Wucherpfennig, T. G.; Pattabiraman, V. R.; Limberg, F. R. P.; Ruiz-Rodríguez, J.; Bode, J. W. "Traceless Preparation of C-Terminal α-Ketoacids for Chemical Protein Synthesis by α-Ketoacid–Hydroxylamine Ligation: Synthesis of SUMO2/3" Angew. Chem. Int. Ed. 201453, 12248–12252.

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(98) Wucherpfennig, T. G.; Rohrbacher, F.; Pattabiraman, V. R.; Bode, J. W. "Formation and Rearrangement of Homoserine Depsipeptides and Depsiproteins in the α-Ketoacid–Hydroxylamine Ligation with 5-Oxaproline" Angew. Chem. Int. Ed. 201453, 12244–12247.
- selected as a Hot Paper.

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(97) Huang, Y.-L.; Bode, J. W. "Synthetic fermentation of bioactive non-ribosomal peptides without organisms, enzymes or reagents" Nature Chem. 20146, 877–884.
- highlighted in C&EN.
- highlighted in Chemistry World.
- InterviewNature Chem. 20146, 846–847.
- highlighted in Nat. Chem. Biol. 201410, 984.

(96) Allen, S. E.; Hsieh, S.-Y.; Gutierrez, O.; Bode, J. W.; Kozlowski, M. C. "Concerted Amidation of Activated Esters: Reaction Path and Origins of Selectivity in the Kinetic Resolution of Cyclic Amines via NHC and Hydroxamic Acid Co-Catalyzed Acyl Transfer" J. Am. Chem. Soc.  2014136, 11783–11791.

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(95) Erős, G.; Kushida, Y.; Bode, J. W. "A Reagent for the One-Step Preparation of Potassium Acyltrifluoroborates (KATs) from Aryl- and Heteroarylhalides" Angew. Chem. Int. Ed. 201453, 7604–7607.
- selected as a Hot Paper.
- reviewed in Synfacts 201410, 1071. 

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(94) Hsieh, S.-Y.; Bode, J. W. "(4aR,9aS)-4-Hydroxy-4,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazin-3(2H)-one" e-EROS 2014, Published Online. (DOI: 10.1002/047084289X.rn01654)

(93) Noda, H.; Bode, J. W. "Synthesis and Chemoselective Ligations of MIDA Acylboronates with O-Me Hydroxylamines" Chem. Sci. 20145, 4328–4332.

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(92) Hsieh, S.-Y.; Wanner, B.; Wheeler, P.; Beauchemin, A. M.; Rovis, T; Bode, J. W. "Stereoelectronic Basis for the Kinetic Resolution of N-Heterocycles with Chiral Acylating Reagents" Chem. Eur. J. 201420, 7228–7231.

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(91) Schäfer, G.; Bode, J. W. "The Synthesis of Sterically Hindered Amides" CHIMIA 201468, 252–255.
- On the occasion of the SCS-Metrohm Foundation Award for best oral presentation at the Fall Meeting 2013.

(90) Noda, H; Erős, G; Bode, J. W. "Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide-Formation" J. Am. Chem. Soc. 2014136, 5611–5614.
- highlighted in C&EN.

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(89) Review article: Vo, C.-V.; Bode, J. W. "Synthesis of Saturated N-Heterocycles" J. Org. Chem. 201479, 2809–2815.
- SnAP reagents are commercially available on SIGMA-ALDRICH!

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(88) Schäfer, G.; Bode, J. W. "Synthesis of Sterically Hindered N-Acylated Amino Acids from N-Carboxyanhydrides" Org. Lett. 201416, 1526–1529.
- reviewed in Synfacts 201410, 635.
- highlighted in Org. Process Res. Dev. 201418, 562–572. 

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(87) Vo, C.-V.; Luescher, M. U.; Bode, J. W. "SnAP Reagents for the One-Step Synthesis of Medium Ring Saturated N-Heterocycles from Aldehydes" Nature Chem. 20146, 310–314.
- highlighted in C&EN.
- highlighted in CHIMIA.
- highlighted in Synfacts 201410, A108.
- SnAP reagents are commercially available on SIGMA-ALDRICH!

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(86) Luescher, M. U.; Vo, C.-V.; Bode, J. W. "SnAP Reagents for the Synthesis of Piperazines and Morpholines" Org. Lett. 201416, 1236–1239.
- highlighted in C&EN.
- abstracted in ChemInform 2014, published online. (DOI: 10.1002/chin.201432028)
- SnAP reagents are commercially available on SIGMA-ALDRICH!

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(85) Review article: Mahatthananchai, J.; Bode, J. W. "On the Mechanism of N-Heterocyclic Carbene-Catalyzed Reactions Involving Acyl Azoliums" Acc. Chem. Res. 201447, 696–707.

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2013

(84) Book chapter: Mahatthananchai, J.; Bode, J. W. "Catalytic Reactions with N-Mesityl Substituted N-Heterocyclic Carbenes" Contemporary Carbene Chemistry 2013, 237–273. [Eds: Robert A. Moss / Michael P. Doyle]

(83) News and views: Bode, J. W. "Carbene catalysis: An internal affair" Nature Chem. 2013, 5, 813–815.

(82) Teichert, J. F.; Mazunin, D.; Bode, J. W. "Chemical Sensing of Polyols with Shapeshifting Boronic Acids as a Self-Contained Sensor Array" J. Am. Chem. Soc. 2013, 135, 11314–11321.
- highlighted in Spotlights on Recent JACS Publications, J. Am. Chem. Soc. 2013, 135, 11679–11679.

(81) Gondo, C. A.; Bode, J. W. "Catalytic Redox Amidations of Aldehydes with a Polymer-Supported Peptide-N-Heterocyclic Carbene Multifunctional Catalyst" Synlett 2013, 24, 1205–1210.
- Cluster Issue on Carbene Catalysis

(80) Vo, C.-V.; Mikutis, G.; Bode, J. W. "SnAP Reagents for the Transformation of Aldehydes into Substituted Thiomorpholines—An Alternative to Cross-Coupling with Saturated Heterocycles" Angew. Chem. Int. Ed. 2013, 52, 1705–1708.
- highlighted in C&EN.
- SnAP reagents are commercially available on SIGMA-ALDRICH!

2012

(78) Chiang, Y.-L; Russak, J. A.; Carrillo, N; Bode, J. W. "Synthesis of Enantiopure Isoxazolidine Monomers for the Preparation of β3-Oligopeptides by Iterative α-Ketoacid–Hydroxylamine (KAHA) Ligations" Helv. Chim. Acta 2012, 2481–2501.
- Dedicated to Professor Dieter Seebach on the occasion of his 75th birthday

(77) He, M.; Rommel, M.; Bode, J. W. "Formal Synthesis of (±)-Clausenamide by NHC-Catalyzed γ-Lactam Formation" Heterocycles 2012, 86, 1689–1696. (Special issue)

(76) Book chapter: Mahatthananchai, J.; Bode, J. W. "Enantioselective Annulations With Chiral N-Mesityl N-Heterocyclic Carbenes" Asymmetric Synthesis: The Essentials II, 2012, 67–77. [Eds: Christmann, Mathias / Bräse, Stefan]

(75) Review article: Mahatthananchai, J.; Dumas, A. M.; Bode, J. W. "Catalytic Selective Synthesis" Angew. Chem. Int. Ed. 2012, 51, 10954–10990.
- Dedicated to Professor Michael P. Doyle on the occasion of his 70th birthday
- highlighted in Org. Process Res. Dev. 2013, 17, 160–168.

5616951

(74) Kreituss, I.; Murakami, Y.; Binanzer, M.; Bode, J. W. "Kinetic Resolution of Nitrogen Heterocycles with a Reusable Polymer-Supported Reagent" Angew. Chem. Int. Ed. 2012, 51, 10660–10663.
- highlighted in Org. Process Res. Dev. 2012, 16, 1674–1683.

9-5

(73) Book Chapter: Bode, J. W. "Reinventing Amide Bond Formation" Top. Organomet. Chem. 2013, 44, 13–33.

(72) Ogunkoya, A. O.; Pattabiraman, V. R.; Bode, J. W. "Sequential α-Ketoacid-Hydroxylamine (KAHA) Ligations: Synthesis of C-Terminal Variants of the Modifier Protein UFM1" Angew. Chem. Int. Ed. 2012, 51, 9693–9697.
- Corrigendum: Angew. Chem. Int. Ed. 2014, 53, 12005.

21

(71) Kravina, A. G., Mahatthananchai, J.; Bode, J. W. "Enantioselective, NHC-Catalyzed Annulations of Trisubstituted Enals and Cyclic N-Sulfonylimines via α,β-Unsaturated Acyl Azoliums" Angew. Chem. Int. Ed. 2012, 51, 9433–9436.

654

(70) Schäfer, G.; Matthey, C.; Bode, J. W. "Facile Synthesis of Sterically Hindered and Electron-Deficient Secondary Amides from Isocyanates" Angew. Chem. Int. Ed. 2012, 51, 9173–9175.
- selected as a Hot Paper.

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(69) Hsieh, S.-Y.; Binanzer, M.; Kreituss, I.; Bode, J. W. "Expanded substrate scope and catalyst optimization for the catalytic kinetic resolution of N-heterocycles" Chem. Commun. 2012, 48, 8892–8894.
- abstracted in ChemInform 2012, published online. (DOI: 10.1002/chin.201249022)

(68) Book chapter: Gondo, C. A.; Bode, J. W. "1,2,4-Triazolium Salts", Science of Synthesis: Houben Weyl Methods of Molecular Transformations, Vol. 13.33, 2012, Georg Thieme Verlag, 199–214. [Ed: B. List]

(67) Allen, S. E.; Mahatthananchai, J.; Bode, J. W.; Kozlowski, M. C. "Oxyanion-steering and CH-π Interactions as Key Elements in a N-Heterocyclic Carbene-Catalyzed [4+2] Cycloaddition" J. Am. Chem. Soc. 2012, 134, 12098–12103
- highlighted in CHIMIA 2012, 66, 801.

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(66) Dumas, A. M., Molander, G. A., Bode, J. W. "Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water" Angew. Chem. Int. Ed. 2012, 51, 5683–5686.

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(65) Dumas, A. M.; Bode, J. W. "Synthesis of Acyltrifluoroborates" Org. Lett. 2012, 14, 2138–2141.
- highlighted in Org. Process Res. Dev. 2012, 16, 1244–1257.

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(63) Larson, K. K.; He, M.; Teichert, J. F.; Naganawa, A.; Bode, J. W. "Chemical Sensing with Shapeshifting Organic Molecules" Chem. Sci. 2012, 3, 1825–1828.
- highlighted in Nature Chem. 2012, 4, 336–337.

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(62) Pattabiraman, V. R.; Ogunkoya, A. O.; Bode, J. W. "Chemical Protein Synthesis by Chemoselective α-Ketoacid–Hydroxylamine (KAHA) Ligations with 5-Oxaproline" Angew. Chem. Int. Ed. 2012, 51, 5114–5118.
- selected as a Hot Paper & Cover.
- Corrigendum: Angew. Chem. Int. Ed. 2014, 53, 12005.

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(61) Gerfaud, T.; Chiang, Y.-L.; Kreituss, I.; Russak, J.; Bode, J. W.; "Enantioselective, chromatography-free synthesis ofβ3-amino acids with natural and unnatural side chains" Org. Process Res. Dev. 2012, 16, 687–696.

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(60) Fukuzumi, T.; Ju, L.; Bode, J. W. "Chemoselective Cyclization of Unprotected Linear Peptides by alpha-Ketoacid–Hydroxyamine Amide-Ligation" Org. Biomol. Chem. 2012, 10, 5837–5844.
- This article is part of the collection: Organic & Biomolecular Chemistry 10th Anniversary.

(59) Book chapter: Chiang, P.-C.; Bode, J. W. "N-Heterocyclic Carbene Catalyzed Reactions of alpha-Functionalized Aldehydes", Science of Synthesis: Asymmetric Organocatalysis, Vol. 1, 2012, Georg Thieme Verlag, 639–672. [Ed: B. List]

(57) Pusterla, I.; Bode, J. W. "The Mechanism of the α-Ketoacid–Hydroxylamine (KAHA) Amide-Forming Ligation" Angew. Chem. Int. Ed. 2012, 51, 513–516.

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(56) Mahatthananchai, J.; Bode, J. W. "The effect of the N-mesityl group in NHC-catalyzed reactions" Chem. Sci. 2012, 3, 192–197.

(55) Huang, Y.-L.; Frey, R; Juarez-Garcia, M. E.; Bode, J. W. "Synthesis of Aza-Surfactin and 3-Epi-aza-surfactin" Heterocycles 2012, 84, 1179–1191

2011

(54) Review article: Pattabiraman, V.; Bode, J. W. "Rethinking Amide Bond Synthesis” Nature 2011, 480, 471–479.

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(53) Binanzer, M.; Hsieh S.-Y.; Bode, J. W. "Catalytic Kinetic Resolution of Cyclic Secondary Amines" J. Am. Chem. Soc. 2011, 133, 19698–19701.
- reviewed in Synfacts 2012, 8, 211.

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(52) Wanner, B.; Mahatthananchai, J.; Bode, J. W. "Enantioselective Synthesis of Dihydropyridinones via NHC-Catalyzed Aza-Claisen Reaction" Org. Lett. 2011, 13, 5378–5381.

1

(51) Schäfer, G.; Bode, J. W. "Friedel-Crafts Benzylation of Activated and Deactivated Arenes" Angew. Chem. Int. Ed. 2011, 50, 10913–10916.
- reviewed in Synfacts 2012, 8, 194.
- highlighted in Org. Process Res. Dev. 2012, 16, 526–534.
- highlighted in Organic Chemistry Portal.

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(50) He, M.; Bode, J. W. "Racemization as a stereochemical measure of dynamics and robustness in shape-shifting organic molecules" Proc. Nat. Acad. Sci. U.S.A. 2011, 36, 14752–14756.

(49) Wu, J.; J. Ruiz-Rodríguez; Comstock, J. M.; Dong, J. Z.; Bode, J. W. "Synthesis of human GLP-1 (7–36) by chemoselective α-ketoacid–hydroxylamine peptide ligation of unprotected fragments" Chem. Sci. 2011, 2, 1976–1979.

4

(48) Vo, C.-V; Mitchell, T. A.; Bode, J. W. "Expanded Substrate Scope and Improved Reactivity of Ether-Forming Cross-Coupling Reactions of Organotrifluoroborates and Acetals" J. Am. Chem. Soc. 2011, 133, 14082–14089.
- highlighted in Organic Chemistry Portal.

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(46) Review article: Chiang, P.-C.; Bode, J. W. "N-Mesityl Substituted Chiral Triazolium Salts: Opening a New World of N-Heterocyclic Carbene Catalysis" TCI MAIL 2011, 149, 2–17.

(45) Chiang, P.-C.; Bode, J. W. "On the Role of CO2 in NHC-Catalyzed Oxidation of Aldehydes" Org. Lett. 2011, 13, 2422–2425.

55

(44) Mahatthananchai, J.; Zheng, P.; Bode, J. W. "α,β-Unsaturated Acyl Azoliums from N-Heterocyclic Carbene Catalyzed Reactions: Observation and Mechanistic Investigation" Angew. Chem. Int. Ed. 2011, 50, 1673–1677.

55

(43) Zheng, P.; Gondo, C. A.; Bode, J. W. "Late-Stage Diversification of Chiral N-Heterocyclic-Carbene Precatalysts for Enantioselectvie Homoenolate Additions" Chem. Asian J. 2011, 6, 614–620.

(42) Book chapter: Hackenberger, C. P. R.; Bode, J. W.; Schwarzer, D. "Chemoselective Peptide Ligation: A Privileged Tool for Protein Synthesis" Amino Acids, Peptides and Proteins in Organic Chemistry: Building Blocks, Catalysis and Coupling Chemistry, Volume 3 (ed A. B. Hughes), 2011.

(41) Review article: Chiang, P.-C.; Bode, J. W. "N-Heterocyclic Carbenes as Organic Catalysts" in N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools; Díez-González, S., Ed.; RSC Catalysis Series No. 6; Royal Society of Chemistry: Cambridge, 2011; pp 399–435. (DOI: 10.1039/9781849732161-00399)

2010

(40) Lippert, A. R.; Naganawa, A.; Keleshian, V. L.; Bode, J. W. "Synthesis of Phototrappable Shape-Shifting Molecules for Adaptive Guest Binding" J. Am. Chem. Soc. 2010, 132, 15790–15799.

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(38) Kaeobamrung, J.; Kozlowski. M. C.; Bode, J. W. "Chiral N-Heterocyclic Carbene-Catalyzed Generation of Ester Enolate Equivalents from α,β-Unsaturated Aldehydes for Enantioselective Diels–Alder Reactions" Proc. Nat. Acad. Sci. U.S.A. 2010, 107, 20661–20665.

(37) Yu, S.; Ishida, H.; Juarez-Garcia, M. E.; Bode, J. W. "Unified synthesis of enantiopure β2h, β3h and β2,3-amino acids" Chem. Sci. 2010, 637–641.

5

(36) Kaeobamrung, J.; Mahatthananchai, J.; Zheng, P.; Bode, J. W. "An Enantioselective Claisen Rearrangement Catalyzed by N-Heterocyclic Carbenes" J. Am. Chem. Soc. 2010, 132, 8810–8812.
- reviewed in Synfacts 2010, issue 09, 1071.

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(31) Flores, M. A.; Bode, J. W. "Chemoselective Protection of α-Ketoacids by Direct Annulations with Oximes" Org. Lett. 2010, 12, 1924–1927.

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(30) Mitchell, T. A.; Bode, J. W. "Synthesis of Dialkyl Ethers from Organotrifluoroborates and Acetal" J. Am. Chem. Soc. 2009, 131,18057–18059.
- reviewed in Synfacts 2010, issue 03, 335.

03

2009

(29) Chiang, P.-C.; Kim, Y.; Bode, J. W. "Catalytic Amide Formation with α'-Hydroxyenones as Acylating Reagents" Chem. Commun., 2009, 4566–4568.
- reviewed in Synfacts 2009, issue 09, 1042.

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(27) Valenta, P.; Drucker, N. A.; Bode, J. W. and Walsh, P. J. "Simple One-pot Conversion of Aldehydes and Ketones to Enals" Org. Lett. 2009, 11, 2117–2119.

8
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(25) Struble, J. R.; Bode, J. W. "Formal Synthesis of Salinosporamide A via NHC-catalyzed Intramolecular Lactonization" Tetrahedron, 2009, 65, 4957–4967.

8

(24) Ishida, H.; Carrillo, N.; Bode, J. W. "Synthesis of an enantiopure isoxazolidine monomer for β3-aspartic acid in chemoselective β-oligopeptide synthesis" Tetrahedron Lett. 2009, 50, 3258–3260.

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(22) Lippert, A. R.; Keleshian, V. L.; Bode, J. W. "Dynamic supramolecular complexation by shapeshifting organic molecules" Org. Biomol. Chem. 2009, 7, 1529–1532.

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2008

(20) Rommel, M.; Fukuzumi, T.; Bode, J. W. "Cyclic Ketimines as Superior Electrophiles for NHC-Catalyzed Homoenolate Additions with Broad Scope and Low Catalyst Loadings" J. Am. Chem. Soc. 2008, 130, 17266–17267.
- reviewed in Synfacts 2009, issue 02, 216.

4

(19) He, M.; Beahm, B. J.; Bode, J. W. "Chiral NHC-Catalyzed Oxodiene Diels−Alder Reactions with alpha-Chloroaldehyde Bisulfite Salts" Org. Lett. 2008, 10, 3817–3820.

(18) Struble, J. R.; Bode, J. W. "A modular synthesis of chiral aminoindanol-derived imidazolium salts" Tetrahedron 2008, 64, 6961–6972.

(17) Ju, L.; Lippert, A. R.; Bode, J. W. "Stereoretentive Synthesis and Chemoselective Amide-Forming Ligations of C-Terminal Peptide alpha-Ketoacids" J. Am. Chem. Soc. 2008, 130, 4253–4255.

(16) Struble, J.R.; Kaeobamrung, J.; Bode, J.W. "Synthesis of an N-Mesityl Substituted Chiral Imidazolium Salt for NHC-Catalyzed Reactions" Org. Lett. 2008, 10, 957–960.
- reviewed in Synfacts 2008, issue 06, 645.

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(15) He, M.; Bode, J. W. "Enantioselective, NHC-Catalyzed Bicyclo-beta-Lactam Formation via Direct Annulations of Enals and Unsaturated N-Sulfonyl Ketimines" J. Am. Chem. Soc. 2008, 130, 418–419.
- reviewed in Synfacts 2008, issue 03, 307.

5464

2007

(14) Bode, J. W.; Sohn, S. S. "N-Heterocyclic Carbene-Catalyzed Redox Amidations of alpha-Functionalized Aldehydes with Amines" J. Am. Chem. Soc. 2007, 129, 13798–13799.

14

(13) Chiang, P.-C.; Kaeobamrung, J.; Bode, J. W. "Enantioselective, Cyclopentene-Forming Annulations via NHC-Catalyzed Benzoin–Oxy-Cope Reactions" J. Am. Chem. Soc. 2007, 129, 3520–3521.
- reviewed in Synfacts 2007, issue 05, 545.

2

2006

(12) He, M.; Uc, G. J.; Bode, J. W. "Chiral, N-Heterocyclic Carbene Catalyzed Oxodiene Diels-Alder Reactions with Low Catalyst Loadings" J. Am. Chem. Soc. 2006, 128, 15088–15089.
- reviewed in Synfacts 2007, issue 01, 100.

12

(11) Review article: Bode, J. W. "Emerging Methods for the Synthesis of Amide and Peptide Bonds" Curr. Opin. Drug Discov. Devel. 2006, 9, 765–775.

(10) Lippert, A. R.; Kaeobamrung, J.; Bode, J. W. "Synthesis of Oligosubstituted Bullvalones: Shapeshifiting Molecules Under Basic Conditions ", J. Am. Chem. Soc. 2006, 128, 14738–14739.

1

(9) Sohn, S. S.; Bode, J. W. "N-Heterocyclic Carbene Catalyzed C–C Bond Cleavage in Redox Esterifications of Chiral Formylcyclopropanes" Angew. Chem. Int. Ed. 2006, 6021–6024.
- reviewed in Synfacts 2006, issue 10, 1060.

5

(8) He, M.; Struble, J. R.; Bode, J. W. "Highly Enantioselective Azadiene Diels-Alder Reactions Catalyzed by Chiral N-Heterocyclic Carbenes" J. Am. Chem. Soc. 2006, 128, 8418–8420.
- reviewed in Synfacts 2006, issue 08, 840.

1

(7) Carrillo, N.; Davalos, E. A.; Russak, J. A.; Bode, J. W. "Iterative, Aqueous Synthesis of b3-oligopeptides without Coupling Reagents" J. Am. Chem. Soc. 2006, 128, 1452-1453.
- highlighted in C&E News.

4

(6) Bode, J. W.; Fox, R. M.; Baucom, K. D. "Decarboxylative Condensations of alpha-Ketoacids and N-Alkylhydroxylamines: A New Amide Ligation Reaction" Angew. Chem. Int. Ed. 2006, 45, 1248-1252.
- highlighted in C&E News.

2005

(5) Sohn, S.; Bode, J. W. "Catalytic Generation of Activated Carboxylates from Enals: A Product Determining Role for the Base" Org. Lett. 2005, 7, 3873-3876.
- categorized in Organic Chemistry Portal.

1212

(4) He, M.; Bode, J. W. "Catalytic Synthesis of gamma-Lactams via Direct Annulations of Enals and N-Sulfonylimines" Org. Lett. 2005, 7, 3131–3134.
- highlighted in Angew. Chem. Int. Ed. 2005, 44, 7506.

555

2004

(3) Bode, J. W. "Reactor, Chem Axon" J. Am. Chem. Soc. 2004, 126, 15317. (Software Review)

(2) Sohn, S. S.; Rosen, E. L.; Bode, J. W. "N-Heterocyclic Carbene-Catalyzed Generation of Homoenolates: gamma-Butyrolactones by Direct Annulations of Enals and Aldehydes" J. Am. Chem. Soc. 2004, 126, 14370-14371.
- highlighted in Angew. Chem. Int. Ed. 2005, 44, 7506.

2

(1) Chow, K. Y.-K.; Bode, J. W. "Catalytic Generation of Activated Carboxylates: Direct, Stereoselective Synthesis of beta-Hydroxyesters from Epoxyaldehydes" J. Am. Chem. Soc. 2004, 126, 8126–8127.
- highlighted in Angew. Chem. Int. Ed. 2005, 44, 7506.

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